Polimery funkcjonalne

Zespół badawczy nr 18

Polimery funkcjonalne

Kierownik zespołu

dr hab. Piyush Sindhu Sharma

Tematyka badawcza

1. Zastosowanie bio-naśladowczych materiałów w katalizie
Projektowanie i synteza polimerów wdrukowanych molekularnie (Molecularly Imprinted Polymers, MIPs) o lukach molekularnych naśladujących działanie centrów aktywnych enzymów.  Zastosowanie tych materiałów w elektro- i fotokatalizie. Projektowanie inteligentnych materiałów w celu ich zastosowania do wykrywania, wydzielania oraz rozkładania substancji toksycznych.

2. Materiały nanostrukturalne

  • Rozwijanie metod syntezy nanostrukturalnych polimerów o rozwiniętej powierzchni z zastosowaniem miękkich lub stałych szablonów
  • Synteza wielofunkcyjnych nanocząstek
  • Osadzanie ultra cienkich wielowarstwowych warstw polimerów funkcyjnych poprzez kontrolowaną polimeryzację oraz ich zastosowanie w konstrukcji chemoczujników

Członkowie

  • dr inż. Maciej Cieplak 
  • dr inż. Kamila Łępicka 
  • dr inż. Krzysztof Noworyta 
  • dr Joanna Piechowska 
  • mgr Monika Mierzejewska
  • mgr Dominik Korol
  • mgr Katarzyna Wielondek

Badania

Designing of Biomimetic Materials

  • Molecularly imprinted polymers (MIPs) – Synthesis of polymers with molecular cavities capable of selective recognition of molecules for devising selective chemosensors.
  • Polymer films with developed surface – Deposition of micro-/nanostructured conductive polymer films for improved chemosensing, and energy storage.
  • Polymer electrocatalysts – Application of conductive polymer films as a selective electrocatalysts.

Publikacje

2021

Mazuryk, J., Sharma, P. S., & Kutner, W.
Molecularly imprinted polymer composites in drug delivery.
Molecularly Imprinted Polymer Composites, https://doi.org/10.1016/B978-0-12-819952-7.00014-7

Lach, P., Cieplak, M., Noworyta, K. R., Pieta, P., Lisowski, W., Kalecki, J., Chitta, R., D’Souza, F., Kutner, W., & Sharma, P. S.
Self-reporting molecularly imprinted polymer with the covalently immobilized ferrocene redox probe for selective electrochemical sensing of p-synephrine.
Sensors and Actuators B: Chemical, https://doi.org/10.1016/j.snb.2021.130276

Jyoti, Gonzato, C., Żołek, T., Maciejewska, D., Kutner, A., Merlier, F., Haupt, K., Sharma, P. S., Noworyta, K. R., & Kutner, W.

Molecularly imprinted polymer nanoparticles-based electrochemical chemosensors for selective determination of cilostazol and its pharmacologically active primary metabolite in human plasma.  

Biosensors and Bioelectronics, https://doi.org/10.1016/J.BIOS.2021.113542 

Yasmeen, N., Etienne, M., Sharma, P. S., El-Kirat-Chatel, S., Helú, M. B., & Kutner, W.
Molecularly imprinted polymer as a synthetic receptor mimic for capacitive impedimetric selective recognition of Escherichia coli K-12.
Analytica Chimica Acta, https://doi.org/10.1016/J.ACA.2021.339177

Ayerdurai, V., Garcia-Cruz, A., Piechowska, J., Cieplak, M., Borowicz, P., Noworyta, K. R., Spolnik, G., Danikiewicz, W., Lisowski, W., Pietrzyk-Le, A., D’Souza, F., Kutner, W., & Sharma, P. S.
Selective Impedimetric Chemosensing of Carcinogenic Heterocyclic Aromatic Amine in Pork by dsDNA-Mimicking Molecularly Imprinted Polymer Film-Coated Electrodes.
Journal of Agricultural and Food Chemistry, https://doi.org/10.1021/ACS.JAFC.1C05084

Jyoti, Rybakiewicz, R., Zolek, T., Maciejewska, D., Gilant, E., Buś-Kwaśnik, K., Kutner, A., Noworyta, K., & Kutner, W.
Cilostazol-imprinted polymer film-coated electrode as an electrochemical chemosensor for selective determination of cilostazol and its active primary metabolite.
Journal of Materials Chemistry B, https://doi.org/10.1039/D1TB02186A

2022

Yasmeen, N., Kalecki, J., Borowicz, P., Kutner, W., & Sharma, P. S.
Electrochemically Initiated Synthesis of Polyacrylamide Microgels and Core-shell Particles.
ACS Applied Polymer Materials,  https://doi.org/10.1021/ACSAPM.1C01359

Bartold, K., Iskierko, Z., Borowicz, P., Noworyta, K., Lin, C.-Y., Kalecki, J., Sharma, P. S., Lin, H.-Y., & Kutner, W.
Molecularly imprinted polymer-based extended-gate field-effect transistor (EG-FET) chemosensor for selective determination of matrix metalloproteinase-1 (MMP-1) protein.
Biosensors and Bioelectronics,  https://doi.org/10.1016/J.BIOS.2022.114203

Łępicka, K., Sharma, P., Borowicz, P., Francius, G., & Walcarius, A.
Get closer to the intrinsic properties of Ni2+salen polymer semiconductors accessed by chain isolation inside silica nanochannels.
Journal of Materials Chemistry C, https://doi.org/10.1039/D2TC00976E

Jyoti, Żołek, T., Maciejewska, D., Gilant, E., Gniazdowska, E., Kutner, A., Noworyta, K. R., & Kutner, W.
Polytyramine Film-Coated Single-Walled Carbon Nanotube Electrochemical Chemosensor with Molecularly Imprinted Polymer Nanoparticles for Duloxetine-Selective Determination in Human Plasma.
ACS Sensors, https://doi.org/10.1021/ACSSENSORS.2C00124

Yasmeen, N., Karpinska, A., Kalecki, J., Kutner, W., Kwapiszewska, K., & Sharma, P. S.

Electrochemically Synthesized Polyacrylamide Gel and Core–Shell Nanoparticles for 3D Cell Culture Formation.

ACS Applied Materials & Interfaces, https://doi.org/10.1021/ACSAMI.2C04904

Mierzejewska, M., Łępicka, K., Kalecki, J., Lisowski, W., & Sharma, P. S.

Ni(OH)2-Type Nanoparticles Derived from Ni Salen Polymers: Structural Design toward Functional Materials for Improved Electrocatalytic Performance.

ACS Applied Materials & Interfaces, https://doi.org/10.1021/ACSAMI.2C06147

Jyoti, Dmitrieva, E., Żołek, T., Maciejewska, D., Rybakiewicz-Sekita, R., Kutner, W., & Noworyta, K. R.
An insight into the polymerization process of the selected carbazole derivatives - why does it not always lead to a polymer formation?
Electrochimica Acta,  https://doi.org/10.1016/J.ELECTACTA.2022.140948

Ayerdurai, V., Lach, P., Lis-Cieplak, A., Cieplak, M., Kutner, W., Sindhu Sharma, P.
An advantageous application of molecularly imprinted polymers in food processing and quality control.
Critical Reviews in Food Science and Nutrition, https://doi.org/10.1080/10408398.2022.2132208

Ayerdurai, V., Cieplak, M., & Kutner, W.
Molecularly imprinted polymer-based electrochemical sensors for food contaminants determination.
Trends in Analytical Chemistry,  https://doi.org/10.1016/J.TRAC.2022.116830

2023

Mater, J., Chem, B., Kalecki, J., Cieplak, M., Iskierko, Z., Piechowska, J., Nogala, W., D’souza, F., & Sharma, P. S.
Post-imprinting modification: electrochemical and scanning electrochemical microscopy studies of a semi-covalently surface imprinted polymer.
Journal of Materials Chemistry B, https://doi.org/10.1039/D2TB02116A
Introduction of redox-active tracer to the imprinted molecular cavities by post-imprinting modification and its confirmation by scanning electrochemical microscopy. 

Korol, D., Kisiel, A., Cieplak, M., Michalska, A., Sharma, P. S., & Maksymiuk, K.
Synthesis of conducting molecularly imprinted polymer nanoparticles for estriol chemosensing.
Sensors and Actuators B: Chemical, https://doi.org/10.1016/J.SNB.2023.133476

Bian, Y., Pan, Q., Zhu, Y., Liang, J., Zhang, Y., Zhang, Y., Zhang, S., Qian, S., Geng, Z., You, Z., Cieplak, M., Sharma, P. S., Zhang, Y., He, Y., & Zhu, B.
Durable conducting polymer electrodes pursue low impedance, antifouling, and electrochemical stress tolerance.
Applied Surface Science,  https://doi.org/10.1016/J.APSUSC.2023.156902