Modified electrodes for potential application in sensors and cells
Group leader
prof. dr hab. Marcin Opałło
Research topics
Electrochemical properties of nanomaterials suspensions. Reactions at liquid-liquid interface. Reactions and catalytic materials for low temperature formic acid fuel cells. Supramolecular chemistry of conducting molecularly imprinted polymers.
Members
- mgr Joanna Dolińska
- mgr Karolina Gołębiewska
- mgr inż. Karol Juchniewicz
- dr Shumaila Razzaque
- mgr Aimen Waqar
- mgr inż. Katarzyna Dusiło
- mgr Rimsha Niazi
- adm. dr inż. Ewa Roźniecka
Research
Electrochemical properties of nanomaterials suspensions. These studies are performed in forced convection conditions: at rotating disc electrode and in flow. Number of reactions like electrocatalytic, electroreduction, electrodissolution and electrochemical redox reactions are employed for detection of nanoparticles in these conditions.
Reactions at liquid-liquid interface. These studies focus on H2 evolution and H2O2 generation also driven by light. The methods of refficiency enhancement by electrochemical regeneration of electrn donor are developed.
Reactions and catalytic materials for low temperature formic acid fuel cells. These studies ifocusdevelopment of new catalyst for formic acid oxidation and hydrogen reduction and construction of new devices.
Supramolecular chemistry of conducting molecularly imprinted polymers. Focused on devising, fabricating, and testing of molecularly imprinted polymer chemosensors based on polymer modified electrodes.
Publications
2021
Mazuryk, J., Sharma, P. S., & Kutner, W.
Molecularly imprinted polymer composites in drug delivery.
Molecularly Imprinted Polymer Composites, https://doi.org/10.1016/B978-0-12-819952-7.00014-7
Safari, F., Tkacz, M., & Katrusiak, A.
High-Pressure Sorption of Hydrogen in Urea.
The Journal of Physical Chemistry C, https://doi.org/10.1021/acs.jpcc.1c00138
Kurzydłowski, D., Kuzovnikov, M. A., & Tkacz, M.
High-pressure phase transition of AB 3 -type compounds: case of tellurium trioxide.
RSC Advances, https://doi.org/10.1039/D1RA02344F
Kuzovnikov, M. A., Antonov, V. E., Ivanov, A. S., Hansen, T., Savvin, S., Kulakov, V. I., Tkacz, M., & Kolesnikov, A. I.
Neutron scattering study of tantalum monohydride and monodeuteride.
International Journal of Hydrogen Energy, https://doi.org/10.1016/j.ijhydene.2021.03.149
Warczak, M., Gniadek, M., Hermanowski, K., & Osial, M.
Well-defined polyindole–Au NPs nanobrush as a platform for electrochemical oxidation of ethanol.
Pure and Applied Chemistry, https://doi.org/10.1515/pac-2020-1101
Kalisz, J., Nogala, W., Adamiak, W., Gocyla, M., Girault, H. H., & Opallo, M.
The Solvent Effect on H2O2 Generation at Room Temperature Ionic Liquid|Water Interface.
ChemPhysChem, https://doi.org/10.1002/cphc.202100219
Mazuryk, J., Puchalska, I., Koziński, K., Ślusarz, M. J., Ruczyński, J., Rekowski, P., Rogujski, P., Płatek, R., Wiśniewska, M. B., Piotrowski, A., Janus, Ł., Skowron, P. M., Pikuła, M., Sachadyn, P., Rodziewicz-Motowidło, S., Czupryn, A., & Mucha, P.
PTD4 Peptide Increases Neural Viability in an In Vitro Model of Acute Ischemic Stroke.
International Journal of Molecular Sciences, https://doi.org/10.3390/ijms22116086
Lach, P., Cieplak, M., Noworyta, K. R., Pieta, P., Lisowski, W., Kalecki, J., Chitta, R., D’Souza, F., Kutner, W., & Sharma, P. S.
Self-reporting molecularly imprinted polymer with the covalently immobilized ferrocene redox probe for selective electrochemical sensing of p-synephrine.
Sensors and Actuators B: Chemical, https://doi.org/10.1016/j.snb.2021.130276
Jyoti, Gonzato, C., Żołek, T., Maciejewska, D., Kutner, A., Merlier, F., Haupt, K., Sharma, P. S., Noworyta, K. R., & Kutner, W.
Molecularly imprinted polymer nanoparticles-based electrochemical chemosensors for selective determination of cilostazol and its pharmacologically active primary metabolite in human plasma.
Biosensors and Bioelectronics, https://doi.org/10.1016/J.BIOS.2021.113542
Ayom, G. E., Khan, M. D., Choi, J., Gupta, R. K., Zyl, W. E. van, & Revaprasadu, N.
Synergistically enhanced performance of transition-metal doped Ni2P for supercapacitance and overall water splitting.
Dalton Transactions, https://doi.org/10.1039/D1DT01058A
Khan, M. D., Opallo, M., & Revaprasadu, N.
Colloidal synthesis of metal chalcogenide nanomaterials from metal–organic precursors and capping ligand effect on electrocatalytic performance: progress, challenges and future perspectives.
Dalton Transactions, https://doi.org/10.1039/D1DT01742J
Majchrowicz, A., Roguska, A., Majchrowicz, K., Pisarek, M., Hołdyński, M., Bazarnik, P., & Lewandowska, M.
Influence of microstructural features on the growth of nanotubular oxide layers on β-phase Ti-24Nb-4Zr-8Sn and α + β-phase Ti-13Nb-13Zr alloys.
Surface and Coatings Technology, https://doi.org/10.1016/J.SURFCOAT.2021.127695
Yasmeen, N., Etienne, M., Sharma, P. S., El-Kirat-Chatel, S., Helú, M. B., & Kutner, W.
Molecularly imprinted polymer as a synthetic receptor mimic for capacitive impedimetric selective recognition of Escherichia coli K-12.
Analytica Chimica Acta, https://doi.org/10.1016/J.ACA.2021.339177
Kuzovnikov, M. A., Antonov, V. E., Hansen, T., Ivanov, A. S., Kolesnikov, A. I., Kulakov, V. I., Muzalevsky, V. D., Savvin, S., & Tkacz, M.
Isotopic dependence of the frequency of optical vibrations in molybdenum monohydride.
Journal of Alloys and Compounds, https://doi.org/10.1016/J.JALLCOM.2021.162299
Ayerdurai, V., Garcia-Cruz, A., Piechowska, J., Cieplak, M., Borowicz, P., Noworyta, K. R., Spolnik, G., Danikiewicz, W., Lisowski, W., Pietrzyk-Le, A., D’Souza, F., Kutner, W., & Sharma, P. S.
Selective Impedimetric Chemosensing of Carcinogenic Heterocyclic Aromatic Amine in Pork by dsDNA-Mimicking Molecularly Imprinted Polymer Film-Coated Electrodes.
Journal of Agricultural and Food Chemistry, https://doi.org/10.1021/ACS.JAFC.1C05084
Jyoti, Rybakiewicz, R., Zolek, T., Maciejewska, D., Gilant, E., Buś-Kwaśnik, K., Kutner, A., Noworyta, K., & Kutner, W.
Cilostazol-imprinted polymer film-coated electrode as an electrochemical chemosensor for selective determination of cilostazol and its active primary metabolite.
Journal of Materials Chemistry B, https://doi.org/10.1039/D1TB02186A
2022
Yasmeen, N., Kalecki, J., Borowicz, P., Kutner, W., & Sharma, P. S.
Electrochemically Initiated Synthesis of Polyacrylamide Microgels and Core-shell Particles.
ACS Applied Polymer Materials, https://doi.org/10.1021/ACSAPM.1C01359
Ayom, G. E., Khan, M. D., Masikane, S. C., De Souza, F., Lin, W., Gupta, R. K., & Revaprasadu, N.
Phase transformations in the nickel phosphide system induced by transition-metal doping and their electro-catalytic study.
Sustainable Energy & Fuels, https://doi.org/10.1039/D1SE01866C
Antonov, V. E., Fedotov, V. K., Ivanov, A. S., Kolesnikov, A. I., Kuzovnikov, M. A., Tkacz, M., & Yartys, V. A.
Lattice dynamics of high-pressure hydrides studied by inelastic neutron scattering.
Journal of Alloys and Compounds, https://doi.org/10.1016/J.JALLCOM.2022.164208
Bartold, K., Iskierko, Z., Borowicz, P., Noworyta, K., Lin, C.-Y., Kalecki, J., Sharma, P. S., Lin, H.-Y., & Kutner, W.
Molecularly imprinted polymer-based extended-gate field-effect transistor (EG-FET) chemosensor for selective determination of matrix metalloproteinase-1 (MMP-1) protein.
Biosensors and Bioelectronics, https://doi.org/10.1016/J.BIOS.2022.114203
Pisarek, M., Ambroziak, R., Hołdyński, M., Roguska, A., Majchrowicz, A., Wysocki, B., & Kudelski, A.
Nanofunctionalization of Additively Manufactured Titanium Substrates for Surface-Enhanced Raman Spectroscopy Measurements.
Materials, https://doi.org/10.3390/MA15093108
Jyoti, Żołek, T., Maciejewska, D., Gilant, E., Gniazdowska, E., Kutner, A., Noworyta, K. R., & Kutner, W.
Polytyramine Film-Coated Single-Walled Carbon Nanotube Electrochemical Chemosensor with Molecularly Imprinted Polymer Nanoparticles for Duloxetine-Selective Determination in Human Plasma.
ACS Sensors, https://doi.org/10.1021/ACSSENSORS.2C00124
Jaroń, T. J., Ying, J., Tkacz, M., Grzelak, A., Prakapenka, V. B., Struzhkin, V. V, & Grochala, W.
Synthesis, Structure, and Electric Conductivity of Higher Hydrides of Ytterbium at High Pressure.
Inorganic Chemistry. https://doi.org/10.1021/ACS.INORGCHEM.2C00405
Yasmeen, N., Karpinska, A., Kalecki, J., Kutner, W., Kwapiszewska, K., & Sharma, P. S.
Electrochemically Synthesized Polyacrylamide Gel and Core–Shell Nanoparticles for 3D Cell Culture Formation.
ACS Applied Materials & Interfaces, https://doi.org/10.1021/ACSAMI.2C04904
Jyoti, Dmitrieva, E., Żołek, T., Maciejewska, D., Rybakiewicz-Sekita, R., Kutner, W., & Noworyta, K. R.
An insight into the polymerization process of the selected carbazole derivatives - why does it not always lead to a polymer formation?
Electrochimica Acta, https://doi.org/10.1016/J.ELECTACTA.2022.140948
Dolinska, J., Holdynski, M., & Opallo, M.
The electrochemical behaviour of suspended Prussian Blue nanoparticles in forced convection conditions.
Journal of Electroanalytical Chemistry, https://doi.org/10.1016/J.JELECHEM.2022.116698
Kuzovnikov, M. A., Antonov, V. E., Hansen, T., Ivanov, A. S., Kolesnikov, A. I., Kulakov, V. I., Muzalevsky, V. D., Savvin, S., & Tkacz, M.
Isotopic dependence of the frequency of optical vibrations in molybdenum monohydride.
Journal of Alloys and Compounds, https://doi.org/10.1016/J.JALLCOM.2021.162299
Antonov, V. E., Fedotov, V. K., Ivanov, A. S., Kolesnikov, A. I., Kuzovnikov, M. A., Tkacz, M., & Yartys, V. A.
Lattice dynamics of high-pressure hydrides studied by inelastic neutron scattering.
Journal of Alloys and Compounds, https://doi.org/10.1016/J.JALLCOM.2022.164208
Ayerdurai, V., Lach, P., Lis-Cieplak, A., Cieplak, M., Kutner, W., Sindhu Sharma, P.
An advantageous application of molecularly imprinted polymers in food processing and quality control.
Critical Reviews in Food Science and Nutrition, https://doi.org/10.1080/10408398.2022.2132208
Ayerdurai, V., Cieplak, M., & Kutner, W.
Molecularly imprinted polymer-based electrochemical sensors for food contaminants determination.
Trends in Analytical Chemistry, https://doi.org/10.1016/J.TRAC.2022.116830
B., Kalecki, J., Cieplak, M., Iskierko, Z., Piechowska, J., Nogala, W., D’souza, F., & Sharma, P. S.
Post-imprinting modification: electrochemical and scanning electrochemical microscopy studies of a semi-covalently surface imprinted polymer.
Journal of Materials Chemistry B, https://doi.org/10.1039/D2TB02116A
Introduction of redox-active tracer to the imprinted molecular cavities by post-imprinting modification and its confirmation by scanning electrochemical microscopy.
Cooperation
- University of Oldenburg, Oldenburg, Germany, Gunther Wittstock, Scanning Electrochemical Microscopy.
- Ecole Polytechnique de Lausanne, Sion, Switzerland, Hubert H. Girault, Reactions at liquid-liquid interface.
- University of Turku, Turku, Finland, Pekka Peljo, Reactions at liquid-liquid interface,
- Tatung University, Taipei, Taiwan, Lin Hong-Ming.Yuh-Jing Chiou, Development of formic acid fuel cells.
- University of North Texas, Denton, USA. Francis D’Souza, Molecular imprinting for chemosensing of chosen food toxins including devising and fabricating of molecularly imprinted polymer film based chemosensors for selective detection and determination of food quality markers and for selective electrocatalysis and photocatalysis.
- University of Guelph, Guelph, Canada. Jacek Lipkowski. Spectroelectrochemical studies of amyloid β impact on the properties of a floating bilayer lipid membrane mimicking brain cell membrane.
- Laboratory of Physical Chemistry and Microbiology for the Environment (LCPME), UMR 7564. Mathieu Etienne, Villers-lès-Nancy, France, Molecular imprinting in polymers for selective chemosensing of autism biomarkers and pathogenic bacteria.
Financing
- Development of formic acid fuel cell batteries as a power supply for portable electrical devices, 2019-2022.
- Nanoelectrodes in Picoliter Droplets: Towards Single Molecules Chemistry, 2018-2020.
- Photoproduction of hydrogen in biphasic systems with electron donor recycling 2020-2023.
- On Chip Whispering Gallery Mode Optical Microcavities for Emerging Contaminant Determination in Waters 2018- 2021.
- Sensing biomarkers of idiopathic pulmonary fibrosis (IPF) with molecularly imprinted polymer-based field effect transistor arrays. 2019-2022.
- NAMES: Molecularly imprinted polymers for selective electrocatalysis and photocatalysis; Interaction of antimicrobial peptides (AMPs) with model bacterial cell membranes; Chemosensors for selective determination of autism biomarkers; Molecularly imprinted polymers for selective electrocatalysis and photocatalysis. 2017-2021.