Modified electrodes for potential application in sensors and cells

Research group no. 23

Modified electrodes for potential application in sensors and cells

Group leader

prof. dr hab. Marcin Opałło

Research topics

Porous organic polymers and their application in electrocatalysis. Electrochemical reactions at liquid-liquid interface. Electrochemical properties of emulsions and suspensions.

Members

  • mgr Karolina Gołębiewska 
  • dr Shumaila Razzaque
  • mgr inż. Katarzyna Dusiło
  • adm. dr inż. Ewa Roźniecka
  • mgr Katarzyna Wielondek

Research

Electrochemical properties of nanomaterials suspensions. These studies are performed in forced convection conditions: at rotating disc electrode and in flow. Number of reactions like electrocatalytic, electroreduction, electrodissolution and electrochemical redox reactions are employed for detection of nanoparticles in these conditions.

Reactions at liquid-liquid interface. These studies focus on H2 evolution and H2O2 generation also driven by light. The methods of refficiency enhancement by electrochemical regeneration of electrn donor are developed.

Reactions and catalytic materials for low temperature formic acid fuel cells. These studies ifocusdevelopment of new catalyst for formic acid oxidation and hydrogen reduction and construction of new devices.

Supramolecular chemistry of conducting molecularly imprinted polymers. Focused on devising, fabricating, and testing of molecularly imprinted polymer chemosensors based on polymer modified electrodes.

Publications

2021

Mazuryk, J., Sharma, P. S., & Kutner, W.
Molecularly imprinted polymer composites in drug delivery.
Molecularly Imprinted Polymer Composites, https://doi.org/10.1016/B978-0-12-819952-7.00014-7

Safari, F., Tkacz, M., & Katrusiak, A.
High-Pressure Sorption of Hydrogen in Urea.
The Journal of Physical Chemistry C, https://doi.org/10.1021/acs.jpcc.1c00138

Kurzydłowski, D., Kuzovnikov, M. A., & Tkacz, M.
High-pressure phase transition of AB 3 -type compounds: case of tellurium trioxide.
RSC Advances, https://doi.org/10.1039/D1RA02344F

Kuzovnikov, M. A., Antonov, V. E., Ivanov, A. S., Hansen, T., Savvin, S., Kulakov, V. I., Tkacz, M., & Kolesnikov, A. I.
Neutron scattering study of tantalum monohydride and monodeuteride.
International Journal of Hydrogen Energy, https://doi.org/10.1016/j.ijhydene.2021.03.149

Warczak, M., Gniadek, M., Hermanowski, K., & Osial, M.
Well-defined polyindole–Au NPs nanobrush as a platform for electrochemical oxidation of ethanol.
Pure and Applied Chemistry, https://doi.org/10.1515/pac-2020-1101

Kalisz, J., Nogala, W., Adamiak, W., Gocyla, M., Girault, H. H., & Opallo, M.
The Solvent Effect on H2O2 Generation at Room Temperature Ionic Liquid|Water Interface.
ChemPhysChem, https://doi.org/10.1002/cphc.202100219

Mazuryk, J., Puchalska, I., Koziński, K., Ślusarz, M. J., Ruczyński, J., Rekowski, P., Rogujski, P., Płatek, R., Wiśniewska, M. B., Piotrowski, A., Janus, Ł., Skowron, P. M., Pikuła, M., Sachadyn, P., Rodziewicz-Motowidło, S., Czupryn, A., & Mucha, P.
PTD4 Peptide Increases Neural Viability in an In Vitro Model of Acute Ischemic Stroke.
International Journal of Molecular Sciences, https://doi.org/10.3390/ijms22116086

Lach, P., Cieplak, M., Noworyta, K. R., Pieta, P., Lisowski, W., Kalecki, J., Chitta, R., D’Souza, F., Kutner, W., & Sharma, P. S.
Self-reporting molecularly imprinted polymer with the covalently immobilized ferrocene redox probe for selective electrochemical sensing of p-synephrine.
Sensors and Actuators B: Chemical, https://doi.org/10.1016/j.snb.2021.130276

Jyoti, Gonzato, C., Żołek, T., Maciejewska, D., Kutner, A., Merlier, F., Haupt, K., Sharma, P. S., Noworyta, K. R., & Kutner, W.

Molecularly imprinted polymer nanoparticles-based electrochemical chemosensors for selective determination of cilostazol and its pharmacologically active primary metabolite in human plasma.  

Biosensors and Bioelectronics, https://doi.org/10.1016/J.BIOS.2021.113542 

Ayom, G. E., Khan, M. D., Choi, J., Gupta, R. K., Zyl, W. E. van, & Revaprasadu, N.  

Synergistically enhanced performance of transition-metal doped Ni2P for supercapacitance and overall water splitting.  

Dalton Transactions, https://doi.org/10.1039/D1DT01058A 

Khan, M. D., Opallo, M., & Revaprasadu, N.  

Colloidal synthesis of metal chalcogenide nanomaterials from metal–organic precursors and capping ligand effect on electrocatalytic performance: progress, challenges and future perspectives.  

Dalton Transactions, https://doi.org/10.1039/D1DT01742J 

Majchrowicz, A., Roguska, A., Majchrowicz, K., Pisarek, M., Hołdyński, M., Bazarnik, P., & Lewandowska, M.

Influence of microstructural features on the growth of nanotubular oxide layers on β-phase Ti-24Nb-4Zr-8Sn and α + β-phase Ti-13Nb-13Zr alloys.

Surface and Coatings Technology,  https://doi.org/10.1016/J.SURFCOAT.2021.127695

Yasmeen, N., Etienne, M., Sharma, P. S., El-Kirat-Chatel, S., Helú, M. B., & Kutner, W.
Molecularly imprinted polymer as a synthetic receptor mimic for capacitive impedimetric selective recognition of Escherichia coli K-12.
Analytica Chimica Acta, https://doi.org/10.1016/J.ACA.2021.339177

Kuzovnikov, M. A., Antonov, V. E., Hansen, T., Ivanov, A. S., Kolesnikov, A. I., Kulakov, V. I., Muzalevsky, V. D., Savvin, S., & Tkacz, M.
Isotopic dependence of the frequency of optical vibrations in molybdenum monohydride.
Journal of Alloys and Compounds, https://doi.org/10.1016/J.JALLCOM.2021.162299

Ayerdurai, V., Garcia-Cruz, A., Piechowska, J., Cieplak, M., Borowicz, P., Noworyta, K. R., Spolnik, G., Danikiewicz, W., Lisowski, W., Pietrzyk-Le, A., D’Souza, F., Kutner, W., & Sharma, P. S.
Selective Impedimetric Chemosensing of Carcinogenic Heterocyclic Aromatic Amine in Pork by dsDNA-Mimicking Molecularly Imprinted Polymer Film-Coated Electrodes.
Journal of Agricultural and Food Chemistry, https://doi.org/10.1021/ACS.JAFC.1C05084

Jyoti, Rybakiewicz, R., Zolek, T., Maciejewska, D., Gilant, E., Buś-Kwaśnik, K., Kutner, A., Noworyta, K., & Kutner, W.
Cilostazol-imprinted polymer film-coated electrode as an electrochemical chemosensor for selective determination of cilostazol and its active primary metabolite.
Journal of Materials Chemistry B, https://doi.org/10.1039/D1TB02186A

2022

Yasmeen, N., Kalecki, J., Borowicz, P., Kutner, W., & Sharma, P. S.
Electrochemically Initiated Synthesis of Polyacrylamide Microgels and Core-shell Particles.
ACS Applied Polymer Materials,  https://doi.org/10.1021/ACSAPM.1C01359

Ayom, G. E., Khan, M. D., Masikane, S. C., De Souza, F., Lin, W., Gupta, R. K., & Revaprasadu, N.
Phase transformations in the nickel phosphide system induced by transition-metal doping and their electro-catalytic study.
Sustainable Energy & Fuels, https://doi.org/10.1039/D1SE01866C

Antonov, V. E., Fedotov, V. K., Ivanov, A. S., Kolesnikov, A. I., Kuzovnikov, M. A., Tkacz, M., & Yartys, V. A.
Lattice dynamics of high-pressure hydrides studied by inelastic neutron scattering.
Journal of Alloys and Compounds,  https://doi.org/10.1016/J.JALLCOM.2022.164208

Bartold, K., Iskierko, Z., Borowicz, P., Noworyta, K., Lin, C.-Y., Kalecki, J., Sharma, P. S., Lin, H.-Y., & Kutner, W.
Molecularly imprinted polymer-based extended-gate field-effect transistor (EG-FET) chemosensor for selective determination of matrix metalloproteinase-1 (MMP-1) protein.
Biosensors and Bioelectronics,  https://doi.org/10.1016/J.BIOS.2022.114203

Pisarek, M., Ambroziak, R., Hołdyński, M., Roguska, A., Majchrowicz, A., Wysocki, B., & Kudelski, A.
Nanofunctionalization of Additively Manufactured Titanium Substrates for Surface-Enhanced Raman Spectroscopy Measurements.
Materials, https://doi.org/10.3390/MA15093108

Jyoti, Żołek, T., Maciejewska, D., Gilant, E., Gniazdowska, E., Kutner, A., Noworyta, K. R., & Kutner, W.
Polytyramine Film-Coated Single-Walled Carbon Nanotube Electrochemical Chemosensor with Molecularly Imprinted Polymer Nanoparticles for Duloxetine-Selective Determination in Human Plasma.
ACS Sensors, https://doi.org/10.1021/ACSSENSORS.2C00124

Jaroń, T. J., Ying, J., Tkacz, M., Grzelak, A., Prakapenka, V. B., Struzhkin, V. V, & Grochala, W.
Synthesis, Structure, and Electric Conductivity of Higher Hydrides of Ytterbium at High Pressure.
Inorganic Chemistry. https://doi.org/10.1021/ACS.INORGCHEM.2C00405

Yasmeen, N., Karpinska, A., Kalecki, J., Kutner, W., Kwapiszewska, K., & Sharma, P. S.

Electrochemically Synthesized Polyacrylamide Gel and Core–Shell Nanoparticles for 3D Cell Culture Formation.

ACS Applied Materials & Interfaces, https://doi.org/10.1021/ACSAMI.2C04904

Jyoti, Dmitrieva, E., Żołek, T., Maciejewska, D., Rybakiewicz-Sekita, R., Kutner, W., & Noworyta, K. R.
An insight into the polymerization process of the selected carbazole derivatives - why does it not always lead to a polymer formation?
Electrochimica Acta,  https://doi.org/10.1016/J.ELECTACTA.2022.140948

Dolinska, J., Holdynski, M., & Opallo, M.
The electrochemical behaviour of suspended Prussian Blue nanoparticles in forced convection conditions.
Journal of Electroanalytical Chemistry,  https://doi.org/10.1016/J.JELECHEM.2022.116698

Kuzovnikov, M. A., Antonov, V. E., Hansen, T., Ivanov, A. S., Kolesnikov, A. I., Kulakov, V. I., Muzalevsky, V. D., Savvin, S., & Tkacz, M.
Isotopic dependence of the frequency of optical vibrations in molybdenum monohydride.
Journal of Alloys and Compounds, https://doi.org/10.1016/J.JALLCOM.2021.162299

Antonov, V. E., Fedotov, V. K., Ivanov, A. S., Kolesnikov, A. I., Kuzovnikov, M. A., Tkacz, M., & Yartys, V. A.
Lattice dynamics of high-pressure hydrides studied by inelastic neutron scattering.
Journal of Alloys and Compounds, https://doi.org/10.1016/J.JALLCOM.2022.164208

Ayerdurai, V., Lach, P., Lis-Cieplak, A., Cieplak, M., Kutner, W., Sindhu Sharma, P.
An advantageous application of molecularly imprinted polymers in food processing and quality control.
Critical Reviews in Food Science and Nutrition, https://doi.org/10.1080/10408398.2022.2132208

Ayerdurai, V., Cieplak, M., & Kutner, W.
Molecularly imprinted polymer-based electrochemical sensors for food contaminants determination.
Trends in Analytical Chemistry,  https://doi.org/10.1016/J.TRAC.2022.116830

B., Kalecki, J., Cieplak, M., Iskierko, Z., Piechowska, J., Nogala, W., D’souza, F., & Sharma, P. S.
Post-imprinting modification: electrochemical and scanning electrochemical microscopy studies of a semi-covalently surface imprinted polymer.
Journal of Materials Chemistry B, https://doi.org/10.1039/D2TB02116A
Introduction of redox-active tracer to the imprinted molecular cavities by post-imprinting modification and its confirmation by scanning electrochemical microscopy. 

2023

Ayerdurai Viknasvarri; Cieplak Maciej; Kutner Włodzimierz         

Molecularly imprinted polymer-based electrochemical sensors for food contaminants determination

TRAC-TRENDS IN ANALYTICAL CHEMISTRY 2023 158 116830

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Lach Patrycja; Garcia-Cruz Alvaro; Canfarotta Francesco; Groves Alistair; Kałęcki Jakub; Korol Dominik; Borowicz Paweł; Nikiforow Kostiantyn; Cieplak Maciej; Kutner Włodzimierz; Piletsky Sergey A.; Sharma Piyush Sindhu

Electroactive molecularly imprinted polymer nanop s for selective glyphosate determination

BIOSENSORS & BIOELECTRONICS  2023  236 115381

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Mazuryk Jarosław; Klepacka Katarzyna; Kutner Włodzimierz; Sharma Piyush Sindhu       

Glyphosate Separating and Sensing for Precision Agriculture and Environmental Protection in the Era of Smart Materials

ENVIRONMENTAL SCIENCE & TECHNOLOGY  2023 57 27 9898-9924

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Sudagar Alcina Johnson; Shao Shuai; Zolek Teresa; Maciejewska Dorota; Asztemborska Monika; Cieplak Maciej; Sharma Piyush Sindhu; D'Souza Francis; Kutner Włodzimierz; Noworyta Krzysztof R.

Improving the Selectivity of the C-C Coupled Product Electrosynthesis by Using Molecularly Imprinted Polymer-An Enhanced Route from Phenol to Biphenol           

ACS APPLIED MATERIALS & INTERFACES  2023    15 42 49595-49610

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Celikkin Nehar; Presutti Dario; Maiullari Fabio; Volpi Marina; Promovych Yurii; Gizyński Konrad; Dolińska Joanna; Wiśniewska Agnieszka; Opałło Marcin; Paradiso Alessia; Rinoldi Chiara; Fuoco Claudia; Swieszkowski Wojciech; Bearzi Claudia; Rizzi Roberto; Gargioli Cesare; Costantini Marco

Combining rotary wet-spinning biofabrication and electro-mechanical stimulation for the in vitro production of functional myo-substitutes

BIOFABRICATION  2023 15 4 45012

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Yasmeen Nabila; Etienne Mathieu; Sharma Piyush Sindhu; Kutner Włodzimierz

Artificial receptors for electrochemical sensing of bacteria

CURRENT OPINION IN ELECTROCHEMISTRY 2023 39 101291

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Ehsan Mehwish; Razzaq Humaira; Razzaque Shumaila; Kanwal Memoona; Hussain Irshad

Engineering nanocomposite membranes of sodium alginate-graphene oxide for efficient separation of oil-water and antifouling performance             

JOURNAL OF ENVIRONMENTAL CHEMICAL ENGINEERING 2023  11 1 109185

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Kałęcki Jakub; Cieplak Maciej; Iskierko Zofia; Piechowska Joanna; Nogala Wojciech; D'Souza Francis; Sharma Piyush Sindhu 

Post-imprinting modification: electrochemical and scanning electrochemical microscopy studies of a semi-covalently surface imprinted polymer

JOURNAL OF MATERIALS CHEMISTRY B  2023 11 8 1659-1669

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Lee Mei-Hwa; Lin Cheng-Chih; Kutner Włodzimierz; Thomas James L.; Lin Chu-Yun; Iskierko Zofia; Lin Chien-Yu; Sharma Piyush S.; Lin Hung-Yin 

MoS2 Nanosheet-Doped Peptide-Imprinted Polymer-Coated Electrodes for Electrochemical Determination of CRISPR/dCas9-Activated Protein Expression

ACS APPLIED NANO MATERIALS 2023 6 19 17369-17375

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Dusiło Katarzyna; Siwiec Aleksandra; Hołdyński Marcin; Peljo Pekka; Opałło Marcin        

Formation of an organic film on an electrode via a suspension of redox-active droplets in acidic aqueous solution

ELECTROCHEMISTRY COMMUNICATIONS  2023 154 107544

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Jarosław Mazuryk Katarzyna Klepacka Joanna Piechowska Jakub Kałęcki Ladislav Derzsi Piotr Piotrowski Piotr Paszke Dorota A. Pawlak Simone Berneschi Włodzimierz Kutner and Piyush Sindhu Sharma

In-Capillary Photodeposition of Glyphosate-Containing Polyacrylamide Nanometer-Thick Films

ACS APPLIED POLYMER MATERIALS  2023  5 1 223–235

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Khan Malik Dilshad; Warczak Magdalena; Shombe Ginena Bildard; Revaprasadu Neerish; Opałło Marcin              

Molecular Precursor Routes for Ag-Based Metallic Intermetallic and Metal Sulfide Nanop s: Their Comparative ORR Activity Trend at Solid|Liquid and Liquid|Liquid Interfaces         

INORGANIC CHEMISTRY 2023     62 21 8379-8388

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Malima Nyemaga Masanje; Khan Malik Dilshad; Choi Jonghyun; Gupta Ram K.; Revaprasadu Neerish

Alloying normal and inverse spinel (Zn-Co ferrite) nanostructures via direct precursor pyrolysis for enhanced supercapacitance and water splitting     MATERIALS CHEMISTRY AND PHYSICS    2023      302 127770

Adekoya Joseph Adeyemi; Khan Malik Dilshad; Mlowe Sixberth; Revaprasadu Neerish

Canfieldite Ag8SnS6 nanop s with high light absorption coefficient and quantum yield

MATERIALS CHEMISTRY AND PHYSICS    2023 299 127456

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Lethukuthula Nene; Khan Malik Dilshad; Masikane Siphamandla C.; de Souza Felipe M.; Choi Jonghyun; Gupta Ram K.; Revaprasadu Neerish   

Green synthesis of non-stoichiometric indium sulfide (In2.77S4) nanop s for water splitting and supercapacitance          

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING 2023 156 107252

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Tigwere Gervais A.; Khan Malik D.; Nyamen Linda D.; de Souza Felipe M.; Lin Wang; Gupta Ram K.; Revaprasadu Neerish; Ndifon Peter T.

Transition metal (Ni Cu and Fe) doped MnS nanostructures: Effect of doping on supercapacitance and water splitting   

MATERIALS SCIENCE IN SEMICONDUCTOR PROCESSING 2023 158 107365

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Aboubakr Ahmed Esmail A.; Khan Malik Dilshad; Revaprasadu Neerish; Millet Pierre; Hung Chen-Hsiung; El Rouby Waleed M. A.   

Sn-doped g-C3N4 as a novel photoelectrocatalyst for water oxidation

JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS  2023 176 111242

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Maqbool Muhammad; Akhter Toheed; Hassan Sadaf Ul; Mahmood Asif; Al-Masry Waheed; Razzaque Shumaila

Development of a chromium oxide loaded mesoporous silica as an efficient catalyst for carbon dioxide-free production of ethylene oxide

RSC ADVANCES 2023 13 46 32424-32432

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Razzaq Humaira; Siddique Amna; Farooq Sobia; Razzaque Shumaila; Ahmad Basher; Tahir Saba; Nawaz Hifza

Hybrid ionogel membrane of PVDF incorporating ionic liquid-reduced graphene oxide for the removal of heavy metal ions from synthetic water

MATERIALS SCIENCE AND ENGINEERING B-ADVANCED FUNCTIONAL SOLID-STATE MATERIALS 2023296 116680

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Sibiya Syabonga G.; Ayom Gwaza E.; Khan Malik D.; Choi Jonghyun; Bhoyate Sanket; Gupta Ram K.; Revaprasadu Neerish               

Metal-Organic Precursors for Transition-Metal-Doped Ni2P via Pyrolysis for Efficient Overall Water Splitting and Supercapacitance           

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 2023  26 18

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M.-H. Lee Ch.-Ch. Lin W. Kutner J.L. Thomas Ch.-Y. Lin Z. Iskierko Y.-S. Ku Ch.-Y. Lin P. Borowicz P.S. Sharma Y.-W. Lan Ch.-H. Yang H.-Y. Lin

Peptide-imprinted conductive polymer on continuous monolayer molybdenum disulfide transferred electrodes for electrochemical sensing of Matrix Metalloproteinase-1 in lung cancer culture medium

BIOSENSORS & BIOELECTRONICS X 2023 13 100258

Cooperation

  • University of Oldenburg, Oldenburg, Germany, Gunther Wittstock, Scanning Electrochemical Microscopy.
  • Ecole Polytechnique de Lausanne, Sion, Switzerland, Hubert H. Girault, Reactions at liquid-liquid interface.
  • University of Turku, Turku, Finland, Pekka Peljo, Reactions at liquid-liquid interface,
  • Tatung University, Taipei, Taiwan, Lin Hong-Ming.Yuh-Jing Chiou, Development of formic acid fuel cells.
  • University of North Texas, Denton, USA. Francis D’Souza, Molecular imprinting for chemosensing of chosen food toxins including devising and fabricating of molecularly imprinted polymer film based chemosensors for selective detection and determination of food quality markers and for selective electrocatalysis and photocatalysis.
  • University of Guelph, Guelph, Canada. Jacek Lipkowski. Spectroelectrochemical studies of amyloid β impact on the properties of a floating bilayer lipid membrane mimicking brain cell membrane.
  • Laboratory of Physical Chemistry and Microbiology for the Environment (LCPME), UMR 7564. Mathieu Etienne, Villers-lès-Nancy, France, Molecular imprinting in polymers for selective chemosensing of autism biomarkers and pathogenic bacteria.

Financing

  • Development of formic acid fuel cell batteries as a power supply for portable electrical devices, 2019-2022.
  • Nanoelectrodes in Picoliter Droplets: Towards Single Molecules Chemistry, 2018-2020.
  • Photoproduction of hydrogen in biphasic systems with electron donor recycling 2020-2023.
  • On Chip Whispering Gallery Mode Optical Microcavities for Emerging Contaminant Determination in Waters 2018- 2021.
  • Sensing biomarkers of idiopathic pulmonary fibrosis (IPF) with molecularly imprinted polymer-based field effect transistor arrays. 2019-2022.
  • NAMES: Molecularly imprinted polymers for selective electrocatalysis and photocatalysis; Interaction of antimicrobial peptides (AMPs) with model bacterial cell membranes; Chemosensors for selective determination of autism biomarkers; Molecularly imprinted polymers for selective electrocatalysis and photocatalysis. 2017-2021.